In NYC it is free to dispose of such stuff properly (paid for with taxes). Of the sites I've been to, both have been easily accessible without a car. They've been incredibly easy to use: you walk up and either hand your stuff to the employee or put it in the correct bin yourself based on the signs. I've never had to wait in a line, you just walk in, drop your stuff, and go. And yet every week I still see people disposing of their electronics improperly by putting their smashed televisions on the curb for regular trash pick up instead of taking it to a special waste site. Hell is other people.
https://www.nyc.gov/site/dsny/what-we-do/programs/special-wa...