https://smd.hu/Data/Analog/DSP/SHARC/C&C++%20Compiler%20&%20... says the cc21k compiler for ADSP-21xxx DSP systems has char as 32 bits signed, and that the compiler handles ANSI/ISO standard C.
So I don't believe your statement "sizeof(char) is guaranteed to always be 1" is correct.
> chars are also how you access the byte-level representation of objects in C
Where does the spec say that a char can be used to address any point in an object?
There's all sorts of oddities like tagged architectures which the C spec handles which I know essentially nothing about, but which break common expectations about how C works. I believe this is one of them.
I believe the following is undefined behavior in C, even though your compiler may let you do it, at least sometimes, and on modern desktop hardware:
int i = 12345;
char *s = ((char *)&i) + 1;
char c = *s;
I believe the following is the correct (or less incorrect) way to do it: char tmp[sizeof(int)];
memcpy(tmp, &i, sizeof(int));
char c = tmp[1];