What about kaka?
None of this is scientific (at least, not my attempts to describe it), and I don't have a good explanation for every swear or epithet, but I don't think it would be as satisfying to say "that's lubu!" instead of "that's caca!"
Pi, Pie, Pide, Pita, Pizza, Piadina, Pirog (Russian for "pie"), Piscina (circular basin), Pipe.
Also, some Russian words for organs that have to do with piss (which are naturally circular) also start with "Pi".