Some highlights:
Obama administration backs down on Marijuana Legalization: https://petitions.whitehouse.gov/response/addressing-legaliz...
Army Stops using monkeys (this actually happened in response to this petition as far as I can tell): https://petitions.whitehouse.gov/response/army-no-longer-usi...
National Guard Joint Chief of Staff created: https://petitions.whitehouse.gov/response/chief-national-gua...
This petition (and opinion polls probably) helped prompt the administration to appeal SOPA and PIPA: https://petitions.whitehouse.gov/response/combating-online-p...
This petition (and some campaign promises) have slowly resulted in increased digitization, recently the house put much of their data up in XML: https://petitions.whitehouse.gov/response/digitizing-federal...
This petition is well written if nothing else: https://petitions.whitehouse.gov/response/doubling-and-tripl...
These petitions happened at the same time as (though it's debatable if it resulted in) the president declaring he would not defend DOMA: https://petitions.whitehouse.gov/response/greater-protection...
https://petitions.whitehouse.gov/response/repealing-discrimi...
This petition coincided with a policy change on student loan burden reduction: https://petitions.whitehouse.gov/response/taking-action-redu...