Everything just felt easier, many task where you had to repeat yourself got abstracted away (forms) and the documentation was just awesome one of the main selling points at the time and it still is.
The ORM took me a while to get used to it but after the initial hump i learned it was very powerful and easy to use.
Overall my efficiency went up a lot i was able to prototype in days instead of weeks for feature rich applications. It made me able to toy around with ideas and the first time in my life i had this experience that i hadn't had to fight the framework to get something i wanted.
And you can express yourself so much better in python than php and till today i enjoy the community which is nice and helpful across the board.