John D. Carmack: Armadillo Aerospace http://www.armadilloaerospace.com/n.x/Armadillo/Home
I'm tempted to throw in Google's Sergey Brin (Larry Page too?) for Google Glass.
And I'm sure there are a few others. Elon Musk just shows up more in the news due to his success.
Also, not all billionaires are technically inclined geeks.