Humas produce on the order of 3.10^13 kg of CO2 [1]
Atmosphere weighs 5.1 . 10^18 [2] so the CO2 we produce is 1/100000 (or 0.001%) of the total weight.
Atmosphere contains 0.046% CO2 by weight [3]. So, next year, it's going to be 0.047%
[1] http://www.epa.gov/climatechange/ghgemissions/global.html
[2] http://nssdc.gsfc.nasa.gov/planetary/factsheet/earthfact.htm...
[3] http://www.engineeringtoolbox.com/air-composition-d_212.html