Imo.im supporting Skype and Introducing Voice, Video Capability On All Networks
honeytechblog.com
honeytechblog.com
That'd mean they either partnered with Skype (which would be a first, so I don't think it's likely), or are using Skype client API and rerouting audio from/to it. That's quite a feat, especially if they can manage that in a scalable (wrt the number of users) manner.