Why wouldn't they want to use it for fuel in nuclear reactors?
TL;DR different elements, different concentrations of isotopes.
https://en.wikipedia.org/wiki/MOX_fuel#Fast_reactors
http://www.world-nuclear.org/info/Nuclear-Fuel-Cycle/Fuel-Re...
http://www.huffingtonpost.com/renee-parsons/mox-fuel_b_27078...
Note that there is a separate program that takes excess weapons HEU from Russian stockpiles and downblends it for sale as nuclear fuel. This is the "Megatons to Megawatts" program, and it has downblended almost 500 tons of HEU since 1995.