As an electrical engineer with spacecraft experience, I can say that a car like the Model S isn't likely to electrocute anyone. While extracting someone from a wreck, emergency workers use tools like the "jaws of life", strong metal pliers meant to quickly snip a car's body apart.
When a tool like this cuts into an electric car, if it should slice through a power cable, in most cases the tool would short the cable to the car's chassis, thus grounding it and tripping the safety links that are integral to the battery pack. This means the car will become inoperative, but it doesn't mean anyone will get electrocuted.
I think the above will be the outcome in the vast majority of cases. Compare this to the plight of someone sitting in a wrecked gasoline-fueled car.