Obviously, in the broadest sense, anarchism is relevant to political philosophy because it is the suggestion that governments and therefore politics shouldn't exist. Analogously, atheism is relevant to religion because it is the suggestion that religion is incorrect. And yet, with the definitions I'm explicitly using, anarchism is not politics and atheism is not religion.
And to be clear, there are certainly anarchists (and, much more commonly, minarchists) who blatantly use political methods to achieve their desired results. A prominent example would be Ron Paul, who is arguably an anarchist, but seems to believe that using the condoned political methods to move the USA toward a smaller and more constitutional government is useful. I disagree with these people.