According to the article, you are acting rationally if you are behaving in ways that maximise achievment of your goal(s). So rationality does (tend to) correlate with doing well in the fields you mentioned (excluding law-abidingness, perhaps).
The article seems to be using people's susceptibility to the cognitive biases identified by Daniel Kahneman and Amos Tversky as a measure of rationality.
The author states that there are methods of "fixing" these errors, and that they should be a priority in education, instead of focusing on "intelligence".
As mentioned elsewhere, the community blog http://www.lesswrong.com is dedicated to the pursuit of instrumental rationality.