Summer peak sun hours will be much more than the annual average, when road trips are normally taken. Admittedly, it's not 12 hours, probably closer to 7-8 hours.
Theoretical max efficiency still uses a number of assumptions to get to 40%. If we learned anything from the path of semiconductors, it's that we shouldn't try to predict what's impossible. According to these 10-year predictions, current microprocessors are impossible to manufacture. And so were last year's, and the year before, going all the way back to the 1980s.
I'm not going to accept that infinite range cars are an impossibility. They may be impossible with today's technology, but what about the technology we have 30 years from now? Maybe solar charging is not the way we will do it, but I'm sure we will see it happen.