What do you not get with the CE? No Outlook connector, no Apple iSync plugin, no mobile BES plugin, and no ability to delegate the administration of specific domains to particular users. But for a plug-and-play solution, it's awesome. POP3, IMAP, LDAP, CalDav (including Free/Busy times extensions) work flawlessly. Uses Postfix for the SMTP so you can do lots of tricks behind the scene if necessary. Administration is a breeeze. My company migrated to Zimbra from our home-grown Qmail/CourierIMAP solution, and it's one of the best IT Infrastructure decisions we've ever made.
I administer the CE version at my work and it is a mostly no fuss package and was much better than the collaboration platform that we were using.
Could there be a time where you take a snapshot when the database is writing the transactions to disk and corrupts the snapshots db? or is the LV smart enough to handle that?