Yes. The hstore extension was added to postgres in 2006 (commit 642194ba0cdc0aada9c99bf7712fcae5f3ac86d1), though it predates that date by quite a bit.
The first commit to MongoDB was in 2007
But that doesn't really matter. The reason I dislike MongoDB is that it shipped with unsafe defaults for years and caused people to lose data because of that.
For me, the one must-have feature of a database is that it will always allow me to read the data I've written to it (minus hardware defects). A database which can't fulfill that one feature doesn't qualify as a database in my book.
MySQL has issues there (it allows invalid data to be written and then "corrects" it and I've seen it corrupt table and index data multiple times without any evidence of hardware issues) and so does MongoDB (unless you changed the default config).
This has nothing to do with NoSQL vs. SQL (though, personally, I really like the flexibility for querying offered by the relational model) and everything with data integrity.