stereotypically used in supermarket laser barcode scanner windows. Pretty much indestructible.
You can buy optical flats COTS from the usual optics suppliers. You won't like the price, like $100/square inch.
Maybe a decade after the star trek movie with the whales, I almost got a chance to make a very small fish tank out of transparent aluminum, just like in the movie, using broken supermarket scanner windows. Then they found out how much money they could get by reselling the windows, and my free source dried up before I could make the tank. I was assuming standard aquarium silicone would stick to sapphire just as well as it sticks to glass... anyone out there ever get to try it?