Wikipedia says "the maximum power supported is up to 60 W at 20 V, 36 W at 12 V and 10 W at 5 V" [1]. For a typical 3 metre 20 gauge USB cable 10 W power delivery will cause a voltage drop from 5 to 4.6 V. This is within the +0.25/-0.55 specified for USB 3 [2].
Since nobody can rely on the 5 V from USB to be exactly the charging voltage they need, there will probably be switchmode regulators in-line anyway. Device manufacturers will just have to spec these up a bit to accept higher input voltage if they want more than 10 W.
[1] http://en.wikipedia.org/wiki/USB_Power_Delivery_Specificatio... [2] http://en.wikipedia.org/wiki/USB
If you want 60 watts at 20 v is 3A, and if you want to supply a hundred ports with that you're going to need copper cables the size of your finger.
One of the proposals for residential DC is to supply 380 volts and 24 volts. The higher voltage would be for things like space heaters and hairdryers, while the lower voltage would be for electronics.