For a guy who thinks that x86 is a modern architecture and all architectures that can only do aligned memory access are "older"? I guess it is.
So yes, chips that can only do aligned memory access do tend to be older.
Listen, I know that there are people who worked into retirement without ever seeing anything other than x86 but a) this shows how old x86 is and b) does not give them expertise over different ISAs.
MIPS is still in the top 4 or so CPU architectures by volume, with x86, PPC, and ARM, with ARM as by far the largest (forecast about 3 billion cores licensed last year).
At least a few hundred million MIPS cores are shipped every year. Depending on what you think embedded x86 volume is, it may be ahead of x86. Of course by revenue x86 still beats everyone.
It's a modern ISA, implemented by modern microarchitectures.