For one thing, Sigma appears to have an ortho layout; D3 only does force-directed, right?
The main difference is that sigma only deals with graphs drawing, so it deals without effort with drag and drop (mouse or touch), scaling the graph to the screen, smooth zooming (with mousewheel or pinch)...
Also, sigma does provide in a plugin a force-directed layout, ForceAtlas2, initially developed for Gephi.