node.js 0.6 socket.io 0.9.6
This version of socket.io has a nasty bug in jsonp protocol handling which I patched manually by merging some change from a newer version, but it does work fine.
To make it scale, I run multiple node processes. In the last 300+ days each of those has between 1000 and 2000 concurrent connections all the time and it works fine. Except that there is some memory leak (I'm not sure if it's related to socket.io or some other lib), so I restart each server once a week (it's done automatically each Sunday at 2am).
I had my eye on SockJS since 2012, and it looks like newer versions are really good, but I'd need upgrade to newer nodejs and this is simply not possible for the existing projects as many used modules are not available.
However, if you're starting a new project, it's worth testing and see which performs better.