There is lots of debate if you search google for comparisons, though they usually seem to end up favoring zfs, which is why I'm a little perplexed here.
e.g. http://rudd-o.com/linux-and-free-software/ways-in-which-zfs-...
Notably, I also ran into a show-stopping kernel bug [0] with btrfs within a day or two of the first production rollout of ShipBuilder [1] (it's an open-source self-hosted PaaS Heroku clone). Since switching to zfs there have been zero file-system related issues with any ShipBuilder production or staging environment so far as I am aware.
[0] https://bugs.launchpad.net/ubuntu/+source/linux/+bug/1214085