What's more private, a Word document sitting only on your drive on Windows, or the same information in a Google Doc that you uploaded from a hardened Linux machine over TOR? In that sense, what the desktop runs is becoming less important. In the first case, your file is unlikely to be accessed unless you're a person of significant interest to a government and takes some effort. In the second case, as it was revealed, it's almost routinely scanned or can be accessed with the click of a few buttons. A super secure USB booted secured PC running OpenBSD is not going to help you once the document reaches the internet/cloud.