Yes, there are OpenVMS servers still around. I work with a number of them, and with various folks that are still using them in production.
There are recent builds of OpenSSL for OpenVMS:
http://polarhome.com/openssl/ http://www.openvms.org/stories.php?story=14/04/11/6422157
HP's version is a bit older:
http://h71000.www7.hp.com/openvms/products/ssl/ssl.html
Free OpenVMS accounts: