1. I am not aware of this specific issue. However, I am aware of an issue involving slow pool import with large numbers of zvols. Delphix has developed a fix for it that implements prefix. It should be merged into various Open ZFS platforms soon. It could resolve the problem that you describe.
2. Matthew Ahrens' synctask rewrite fixed this in Open ZFS. It took a while for the fix to propagate to tagged releases, but all Open ZFS platforms should now have it. ZoL gained it with the 0.6.3 release. Here is a link to a page with links to the commits that added this to each platform as well as the months in which the were added: