"Acquia… today announced that its co-founder Dries Buytaert was named CTO of the Year at the 2014 MassTLC Leadership Awards, hosted by the Massachusetts Technology Leadership Council. Acquia led all companies with four finalists at this year’s awards…" [1]
Those examples show that PHP can be used, in a core way, by great technology companies.
[1] http://www.acquia.com/about-us/newsroom/press-releases/dries...