Why not? The worst response you will get is "No".
I would be worried about sending my personal information that appears on my resume (phone numbers, address, full name) unwarranted to someone. I would start by sending a quick email explaining your skills and maybe a link to a portfolio or github, and ask about openings. If they express interest then I would further pursue. If they don't, all they know you by is your email address.
Where it gets into spam is if you send the same copy & pasted text to dozens of possible employers.