Right now, I'm consulting for a large company that still provisions IE6 because it has a bunch of in-house web apps that don't work right on any other browsers. Since switching thousands of users over to another browser could not happen in a single day, these legacy apps would all have to be modified to work in both IE6 and a modern browser. This can be done, but it requires coordination and resources. Furthermore, the groups responsible for the apps and those responsible for the desktop standards probably meet on the org chart at the CIO level.
Sadly, it would be really useful if Chrome (or Firefox or whatever) could accurately emulate IE6's behaviors for sites of an administrator/user's choosing. We could fairly easily make Apache insert a special "PleaseRenderLikeIE6" headers so those applications could continue to function as-is.
Yes, this is painful to write about, but it's the reality of most large corporate IT shops.