1) this does not tell you what the distribution is. Decay is a random process... what is the probability that you have more than 90% of a left at step 1000?
2) this only works because you're taking a limit over an infinite number of atoms, which takes the variance to 0. If you have a discrete system, things become hairier.
Or take the following system for instance:
There are 100 cells, each of which has the same size. At every time step, a little bit of food falls on the cells and is eaten by a single cell. A cell gets the food with a probability proportional to its weight, it then grows by one unit.
If you use expectations, everyone grows at the same rate. If you simulate, you'll see that the results follow a Pareto distribution.