I am pretty sure Google is not blocking calls to nuns because it is trying to be evil. Either they are not a regular phone number, or this is a bug. It's beta. There will be bugs.
I really hope AT&T's whining doesn't ruin this for the rest of us. I love Google Voice, and it would be a shame to see regulations kill it off before it is even out of beta. It's a free service. Why should it have to let me call 900 numbers?