IIRC in the past, there were multiple occassions in which a "button" being pressed in error might have started nuclear war. But I think the guy you are talking about is Stanislav Petrov[1] who is known for preventing nuclear war in 1983[2].
[1]: http://en.wikipedia.org/wiki/Stanislav_Petrov [2]: http://en.wikipedia.org/wiki/1983_Soviet_nuclear_false_alarm...