Only the top-performing enterprise vendors that have been able to get the funding necessary to meet compliance issues AND design have a remote chance of doing decent UI.
Also, another factor to consider is that most enterprise software these days by the typical vendors are acquisitions, so that software has already been around for roughly... 5 years or so. After they're rebranded, it's been another 2 years and the original engineers and designers have left after displeasure with their new masters. And most of these new companies have very little interest in rocking the boat and just want to keep squeezing the existing customers for whatever and will take years and years to introduce the acquired software to their other accounts. So, by then you'll have really, really old software that you just bought.