We found European home educators are often much more "anarchist" in the sense of this article, liberal, free-thinking, non-conforming, often of non-traditional religion / spirituality, who think the state system is too narrow, limited, and structured. In the States it's much more right-wing religious exclusionists who think the system is too liberal, unstructured, and ungodly. A very very weird difference of culture.
My mum wrote a lot about home education, here's her site with all kinds of info about getting started, details about what we did, etc: http://home-ed.info/
I loved it, and it was perfect for me. My brother loves regime and structure, so would probably have done fine in school. I'm much less academic, and do a whole mixture of jobs (acting, teaching, programming, writing, A/V, electronics, etc.) in a non-profit organisation. Almost all stuff that I learned as a kid, with the oceans of free time that I had, and my friends in school didn't. I worked in a theatre company for 3 years, and did school-work in the evenings, or when I had time. I taught myself to code.
With our kids now, my wife (non-home-educated) is a bit skeptical of her ability to home-school. Our son is still too young (he's one). I certainly wouldn't object to him going to school - providing it doesn't interfere with his education too much. :-)