First because what they make from the App Store is spare change for them.
Second because they did have the best browser for a while, and did very much to advance the state of the art (from WebSQL, to Canvas, CSS 3D and other stuff, all originating there, along with the original fast-JITed JS engine who started the JS-race to what we have know). And they did that for years after they had an App platform available too.