If you _only_ want WebSocket connections with no HTTP fallback then Faye WebSocket [2] may be an option. But any production application is going to require fallback for older browsers and pesky proxies/firewalls.
Faye [3] is solid (obviously used Faye WebSocket), has implementations in Node and Ruby, but is a PubSub solution. I'd kinda argue that any real-time app needs at least PubSub functionality anyway.
The ws Node module [4] is apparently "The fastest RFC-6455 WebSocket implementation for Node.js" and receives contributions from 3rd-Eden who is also behind Primus [5]. But it's also WebSocket with no fallback.
I haven't used Primus, but I really like the idea of offering a layer above the underlying connection engine. I've seen contributions to Socket.IO dip in the past (prior to CloudUp being acquired by Automattic), but Socket.IO is used by so many apps that somebody is always likely to maintain it for the foreseeable future. I'm generally in favour of adding abstractions around layers like this (connectivity, DBs, Message Queues, Hosted Services etc.). However, in this case you're then adding a dependency on Primus. Isn't software fun!
[1] https://github.com/igrigorik/em-websocket [2] https://github.com/faye/faye-websocket-node [3] http://faye.jcoglan.com/ [4] https://github.com/websockets/ws [5] https://github.com/primus/primus