The practical side of distributions is package management in every sense. From the point of package management software (dpkg, rpm, apt, yum), repository size (official packages supported), standards in maintenance of the packages, Debian is the winner. That means that your sysadmin work will be much pleasant, and enjoyable. Having to reinstall 100+ servers from CentOS 5 to CentOS 6 will be remembered as the lowest point in my work experience so far. I still regret not convincing my boss to migrate to Debian or Debian based distribution.
I do maintain both rpm and deb packages for the company that I work for, personal projects (only deb) and community. Working on Debian related projects is always nicer and enjoyable, at least for me.