The fact is if you have a serious site there's a good chance SOME specific feature will start looking appealing ( maybe array values, JSON , window functions, a pg extension...). These features are written because people use them, we aren't all writing dead simple CRUD apps. Or you your ORM will interact with one slightly differently than the other. I don't expect to convince any of you doubters, but the first time you get a bug in prod that slipped through the testing process but really could have been caught in dev, you'll ask yourself why you weren't using pg there too.
There's no sane reason to complicate your life by running two databases unless you either have a dead simple app, or are one of the jabbering idealists I see on here. Productive programmers simplify the problem and minimize their tech stacks.