The Nazi rockets blew up too many times. They would have killed at least 10 men trying to leave the atmosphere, and then killed one leaving the atmosphere.
The US took their testing data and combined it with the fruits of Operation Paperclip's R&D to create the Redstone program. The Rocketdyne A7 engine was a direct successor of the A4 and was reliable enough to put the first US astronauts in orbit during the Mercury-Redstone program.
In short, an A4/V-2 would have been reliable enough to serve as the foundation of a British space program as long as it was built to spec without the material substitutions carried out due to wartime shortages.