I've had over 100% luck emailing papers' authors directly asking for a copy of a particular paper I've been interested in reading. I typically get a PDF emailed back to me.
I say "over 100%" because several times I've had hard copies sent for whatever reason with hand-written letters thanking me for expressing interest in their research and letting me know they'd be happy to answer any questions, etc.
I've generally found that some researchers, especially in relatively arcane areas are very pleased to find people who are genuinely interested in their work.
I only appeal to authors directly if I'm unable to access a paper online through my library's JSTOR access which is fairly extensive.