That said, I've not used either in production. But, Nix was the first time I've looked at a new package manager and thought, "OK, someone finally improved on RPM/yum or deb/apt." Most of the time, I look at new package managers and just find myself running down a list of all of the ways they've failed to even replicate the power/flexibility/reliability of those now-ancient package managers, and usually without any really good reason. It's a cool side effect of a superior package manager that so much other stuff comes easily or automatically.
Anyway, this is a really cool idea, and something I want to look into more. You get so much of the "declarative and predictable" elements you want in a service-based architecture for free with Nix, while so many other solutions are bolted on clumsily.