Not an expert, but my understanding is that humans can learn many things through reinforcement learning, but most of our intelligent decisions are a result of unsupervised learning.

For instance, if the stove element was red hot and you touched it, you'd receive a feeling of pain. Reinforcement learning would suggest that you shouldn't do this again, and you might learn to not touch stove elements when they are red hot anymore.

However, a human is likely to additionally realize that touching a red hot marshmallow stick would burn them as well. And at the same time, a human can also tell that a red ball is safe to touch. This sort of behaviour (internally labeling things and deciding what it is that made the stove element dangerous so you can apply that to other things) would be unsupervised learning.