What monopoly? You totally have a choice, it's just that NVIDIA made a large bet on GPGPU and it is paying off for them. You don't see AMD heavily pushing their cards for compute purposes or developing computational developer relations.
It's like saying MATLAB has a monopoly in academic research because so much of the code is written in it. That is slowly changing and moving over to Python now, which is great. Maybe OpenCL will get there someday, but I don't see it happening any time soon.
I would love it if AMD would care more about GPGPU, but they don't, and NVIDIA has little incentive to make their OpenCl drivers equal to their CUDA ones.