That's a lot of books! I wish there were a top 5.
In this list I didn't include quite a number of books I think of as "great" -- instead I put in readable books that I thought would help the target readers.
Just to pick one as an example: I think Newton's "Principia" is a great book. It's not easy to read, and it would not have been a good choice for this group, but it is above any threshold I would draw.