I try to do a combination of sitting and standing to keep my hips from getting too tight, which can end up creating an anterior pelvic tilt that will cause back pain. I'll do couch stretches[1] to open my hip flexors and banded pull-aparts[2] to alleviate some of the rounded shoulder issues that we all get from sitting and typing all day.
1. http://www.bodybuilding.com/images/2016/june/flex-those-flex...
2. http://www.bodybuilding.com/exercises/detail/view/name/band-...
Additionally:
* Try to keep about 20% tension in your abs/core all the time. Even when sitting. Punch your SO in the belly, that always works two ways!
* Don't sit all the time. Walk, stand, etc.
* Certain exercises and stretches can work wonders if you have a _good_ PT who can point out where the problem is.