what else could be done to further vet volunteers? you can't interrogate people or drug them with serums for the truth, so I think it's safe to assume registering is enough.
so, to answer your question, I doubt there is any "guarantee" other than the fact that these are volunteers and you'd have to be a real idiot to falsely register to ensure you can tilt the scales...of bipartisan pairs of Arapahoe County poll volunteers.