dmr wrote the V7 malloc and calloc (which calls malloc) [0,1]. Mike Lesk used calloc in lex ;-) [2]
[0] https://github.com/dspinellis/unix-history-repo/blob/Researc...
[1] https://github.com/dspinellis/unix-history-repo/blob/Researc...
[2] https://github.com/dspinellis/unix-history-repo/blob/Researc...