Parallel index scans will be an absolutely massive win for us. Currently Postgres does not perform any sort of prefetching. When performing an index scan, this results in serialized random I/O. In our case, queries wind up using ~1/10th the I/O they could be using if there were to do more I/O in parallel. We are expecting a dramatic speedup just from parallel index scans. This is in addition to the bugfix in 9.6 (we're currently on 9.5) which added proper support for index only scans over partial indexes. That bugfix should also result in a pretty large speedup for a lot of our queries.
As soon as Postgres 10 comes out, we are immediately going to upgrade. There are just so many huge wins for us.
[0] https://www.postgresql.org/message-id/20161206034955.bh33pae...
[1] https://blog.heapanalytics.com/running-10-million-postgresql...