"The 9-9-9 format was chosen based on the 'button A' and 'button B' design of pre-payment coin-operated public payphones in wide use (first introduced in 1925) which could be easily modified to allow free use of the 9 digit on the rotary dial in addition to the 0 digit (then used to call the operator)"
So there were valid technical reasons, as well as 999 being harder to dial by accident.
https://en.m.wikipedia.org/wiki/999_(emergency_telephone_num...