Even if every other electric appliance in your house doubled or halved its power consumption, it wouldn't move the needle near as much as the biggest energy user in the house.
If your AC is more than 5 years old, consider replacing it. Not only do they eventually wear out, wasting more energy, but newer ones can be more energy-efficient.
Consider buying a cheap mister for your AC's radiator. It uses a small amount of water to conduct the heat off the coils. Cool-n-save, Mist-n-save, Mistbox.. may want to soften the water you use to avoid scale deposits.
The smartest thing would probably be to explore a 5kW PV system on your roof. Not only will it remove heat from your roof but it will also save a lot on your air conditioning no matter how efficient it is nor how hot it gets outside. SC's government and utility incentives (visit dsireusa.org) look a lot like those in PV-friendly states from 5 years ago (which is to say, ridiculously good for the homeowner).