it would be great if every language on their home page, as well as listing how to do common things such as this:
http://www.iolanguage.com/scm/io/docs/IoTutorial.html
would also give a demonstration of what makes this language unusual (beyond syntax).
for io it seems like this might be some smalltalk-inspired message passing stuff:
http://www.iolanguage.com/scm/io/docs/IoGuide.html#Objects-F...
combined with concurrency:
http://www.iolanguage.com/scm/io/docs/IoGuide.html#Concurren...
but it's hard to tell at a glance.
fwiw, the haskell page does a great job of this: following the "why use haskell?" gives the classic quicksort example.