Yes, that vision ultimately needs more than just a third party win. The system itself is broken. It's still a better choice.
I'm not knowledgeable enough about various industrial wastes to comment on environmental issues. If that's what you see as the most important issue, why would you vote anything but Green? That's been a core of their platform for fourty years.
You need to learn Civics. I could write in my own name since my opinions are closer to my opinions than the Green candidate. What would that accomplish?
If, one day, the US introduces proportional or preferred representation then the calculations will change. In Australia, for example, you can vote (1) Green, (2) Labor (say) and then if the Green candidate is eliminated your vote is counted for your second choice. But if the Green candidate gets enough support then you get your first choice.
Even then, Democracy is difficult. In proportional systems, small parties can have disproportionate influence.
I don't think I have the political knowledge or general knowledge to represent my interests best in government, and failing to campaign shows I'm not prepared for the responsibility. I can't say for certain, but I assume it's the same for you. If I'm wrong, you should vote for yourself. I imagine most candidates do.
Yes, some better form of representation is part of my ultimate goal. The fear of small parties having a disproportionate influence doesn't worry me, small groups already have a disproportionate influence.